Issue 8, 2016
From the journal:

Dalton Transactions

Two novel μ6-O2− bridged Co14/Ni14 hydroxamate clusters packed in distorted face-centered cubic patterns†

Yanping Zhang,a   Rui Lv,a   Jingyao Wang,a   Linyan Yang,a   Shengyun Liao,a   Jinlei Tian,a   Wen Gu*a  and  Xin Liu*a  

* Corresponding authors

a Department of Chemistry, Collaborative Innovation Center of Chemical Science and Engineering, Nankai University, and Key Laboratory of Advanced Energy Materials Chemistry (MOE), Tianjin 300071, P. R. China
E-mail: guwen68@nankai.edu.cn, liuxin64@nankai.edu.cn

Abstract

Two novel clusters [CoII14(μ6-O2−)(sbha)12(sba)2 (DMF)7(DMA)]·(DMF)8 (1) and [NiII14(μ6-O2−)(sbha)12(sba)2(DMF)8] (2) (sH2bha = 4-bromo-benzohydroximic acid; sHba = 4-bromobenzene carboxylic acid; DMF = N,N-dimethylformamide; DMA = dimethylamine) have been synthesized. The novel body-centred μ6-O2− bridged Co14 and Ni14 clusters are packed in distorted face-centered cubic (FCC) patterns with different symmetries. Magnetic studies confirmed the antiferromagnetic exchange interactions between magnetic centers.

Graphical abstract: Two novel μ6-O2− bridged Co14/Ni14 hydroxamate clusters packed in distorted face-centered cubic patterns

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Article information

DOI
https://doi.org/10.1039/C5DT03974F
Article type
Communication
Submitted
11 Oct 2015
Accepted
18 Jan 2016
First published
18 Jan 2016

Dalton Trans., 2016,45, 3247-3250

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Two novel μ6-O2− bridged Co14/Ni14 hydroxamate clusters packed in distorted face-centered cubic patterns

Y. Zhang, R. Lv, J. Wang, L. Yang, S. Liao, J. Tian, W. Gu and X. Liu, Dalton Trans., 2016, 45, 3247 DOI: 10.1039/C5DT03974F

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