A new type of photomagnetic system: photoinduced charge transfer in polyoxometalate-based organic–inorganic hybrid†
Abstract
Herein, we show a new photomagnetic system that gives rise to the magnetic transformation from diamagnetism to paramagnetism by photoinduced intramolecular charge transfer in the polyoxometalate-based organic–inorganic hybrid, [(VMo6O22)2{O2C(CH2)2CO2}3] (1).