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Issue 37, 2015

A novel metal–organic framework based on bismuth and trimesic acid: synthesis, structure and properties

Author affiliations

Abstract

A bismuth based metal–organic framework ([Bi(BTC)(DMF)]·DMF (CH3OH)2, Bi–BTC) with a novel topology structure is synthesized by a solvothermal method. Bi–BTC crystalizes in the P21/n space group, exhibits a novel 3D framework consisting of trimesic acid (H3BTC) linked with {Bi2O14} units and contains two helix chains which assemble regularly. In addition, we investigated the photophysical properties of Bi–BTC which shows high activity of O2 production in photocatalysis.

Graphical abstract: A novel metal–organic framework based on bismuth and trimesic acid: synthesis, structure and properties

Supplementary files

Article information


Submitted
12 Aug 2015
Accepted
17 Aug 2015
First published
18 Aug 2015

Dalton Trans., 2015,44, 16238-16241
Article type
Communication

A novel metal–organic framework based on bismuth and trimesic acid: synthesis, structure and properties

G. Wang, Y. Liu, B. Huang, X. Qin, X. Zhang and Y. Dai, Dalton Trans., 2015, 44, 16238 DOI: 10.1039/C5DT03111G

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