Issue 45, 2015

Iron-catalyzed electrochemical C–H perfluoroalkylation of arenes

Abstract

A new iron-catalyzed reaction for the coupling of perfluoroalkyl iodides (RFI) with aromatic substrates is described. The perfluoroalkylated arene products are obtained in good to excellent yields in the presence of a [(bpy)Fe(II)] catalyst (10%) electrochemically regenerated or generated from [(bpy)Fe(III)] at room temperature. The development, scope, and preliminary mechanistic studies of these transformations are reported.

Graphical abstract: Iron-catalyzed electrochemical C–H perfluoroalkylation of arenes

  • This article is part of the themed collection: Fluorine

Supplementary files

Article information

Article type
Paper
Submitted
05 Aug 2015
Accepted
30 Sep 2015
First published
30 Sep 2015

Dalton Trans., 2015,44, 19674-19681

Author version available

Iron-catalyzed electrochemical C–H perfluoroalkylation of arenes

M. Khrizanforov, S. Strekalova, V. Khrizanforova, V. Grinenko, K. Kholin, M. Kadirov, T. Burganov, A. Gubaidullin, T. Gryaznova, O. Sinyashin, L. Xu, D. A. Vicic and Y. Budnikova, Dalton Trans., 2015, 44, 19674 DOI: 10.1039/C5DT03009A

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