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Issue 37, 2015
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An insight into the process and mechanism of a mechanically activated reaction for synthesizing AlH3 nano-composites

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Abstract

The reaction pathway as well as the mechanism of the solid state reaction between MgH2 and AlCl3 has been a mystery so far. Based on SEM, TEM and NMR (Nuclear Magnetic Resonance) analyses, an amorphous intermediate (AlH6)n was preferentially formed and recrystallized as a γ phase at the final stage of the reaction. As a novel finding, this research provides a deep insight into the process and mechanism of this mechanically activated reaction.

Graphical abstract: An insight into the process and mechanism of a mechanically activated reaction for synthesizing AlH3 nano-composites

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Publication details

The article was received on 12 Jul 2015, accepted on 23 Aug 2015 and first published on 26 Aug 2015


Article type: Communication
DOI: 10.1039/C5DT02639C
Dalton Trans., 2015,44, 16251-16255

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    An insight into the process and mechanism of a mechanically activated reaction for synthesizing AlH3 nano-composites

    C. Duan, L. Hu, Y. Sun, H. Zhou and H. Yu, Dalton Trans., 2015, 44, 16251
    DOI: 10.1039/C5DT02639C

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