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Issue 36, 2015
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Single molecule magnet behaviour in a rare trinuclear {CrIIIDy III2} methoxo-bridged complex

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Abstract

The reaction of the chromium(III) chloride tetrahydrofuran complex with the dipivaloylmethane ligand, the lanthanide alcoholic salt DyCl3·CH3OH and the 1,1,1-tris(hydroxymethyl)-ethane ligand resulted in the formation of a new trinuclear chromium–dysprosium complex. Magnetic investigations revealed that the new 3d–4f complex exhibits single molecule magnet behaviour.

Graphical abstract: Single molecule magnet behaviour in a rare trinuclear {CrIIIDyIII2} methoxo-bridged complex

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Supplementary files

Article information


Submitted
29 Jun 2015
Accepted
05 Aug 2015
First published
05 Aug 2015

Dalton Trans., 2015,44, 15769-15773
Article type
Communication
Author version available

Single molecule magnet behaviour in a rare trinuclear {CrIIIDyIII2} methoxo-bridged complex

P. Car, A. Favre, A. Caneschi and R. Sessoli, Dalton Trans., 2015, 44, 15769
DOI: 10.1039/C5DT02459E

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