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Issue 45, 2015
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Reactions of allyl alcohols and boronic acids with trifluoromethanesulfonyl hypervalent iodonium ylide under copper-catalysis

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Abstract

Trifluoromethylsulfinyl and trifluoromethylthio groups are both important substituents for pharmaceuticals, agrochemicals and functional materials. We herein report the trifluoromethylthiolation of allyl alcohols 2 with trifluoromethanesulfonyl hypervalent iodonium ylide 1 under copper catalysis to provide trifluoromethylsulfinyl compounds 3. Trifluoromethylthiolation of boronic acids 4 with 1 furnished trifluoromethylthio compounds 5.

Graphical abstract: Reactions of allyl alcohols and boronic acids with trifluoromethanesulfonyl hypervalent iodonium ylide under copper-catalysis

  • This article is part of the themed collection: Fluorine
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Supplementary files

Article information


Submitted
11 Jun 2015
Accepted
22 Jul 2015
First published
22 Jul 2015

Dalton Trans., 2015,44, 19456-19459
Article type
Communication
Author version available

Reactions of allyl alcohols and boronic acids with trifluoromethanesulfonyl hypervalent iodonium ylide under copper-catalysis

S. Arimori, M. Takada and N. Shibata, Dalton Trans., 2015, 44, 19456
DOI: 10.1039/C5DT02214B

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