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Issue 25, 2015
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Assembly of a large cerium(III)-containing tungstotellurites(IV) nanocluster: [Ce10Te8W88O298(OH)12(H2O)40]18−

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Abstract

A large lanthanide-containing tungstotellurites(IV) nanocluster Na18[Ce10Te8W88O298(OH)12(H2O)40]·54H2O (1) was synthesized by combining cerium linkers and TeO32− heteroanion templates. The macroanion in 1 consists of two identical [Te4W42O144(OH)6Ce4(H2O)13]14− subunits and two triangle-shaped {W2O5Ce(H2O)7} linkers.

Graphical abstract: Assembly of a large cerium(iii)-containing tungstotellurites(iv) nanocluster: [Ce10Te8W88O298(OH)12(H2O)40]18−

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Publication details

The article was received on 06 May 2015, accepted on 19 May 2015 and first published on 20 May 2015


Article type: Communication
DOI: 10.1039/C5DT01711D
Citation: Dalton Trans., 2015,44, 11290-11293

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    Assembly of a large cerium(III)-containing tungstotellurites(IV) nanocluster: [Ce10Te8W88O298(OH)12(H2O)40]18−

    W. Chen, C. Qin, X. Wang, Y. Li, H. Zang, K. Shao, Z. Su and E. Wang, Dalton Trans., 2015, 44, 11290
    DOI: 10.1039/C5DT01711D

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