Issue 20, 2015

Chiral environment of catalytic sites in the chiral metal–organic frameworks

Abstract

Chiral metal–organic frameworks are considered a useful platform in heterogeneous catalysis for enantioselective chemical transformations. However, it has been observed that the enantioselectivity is sensitive to the site at which the reaction takes place, even in a single crystal, since the chiral environment of the catalytic site varies according to its location, e.g., that of the surface is anisotropic, whereas that of the interior is isotropic.

Graphical abstract: Chiral environment of catalytic sites in the chiral metal–organic frameworks

Supplementary files

Article information

Article type
Communication
Submitted
07 Apr 2015
Accepted
13 Apr 2015
First published
13 Apr 2015

Dalton Trans., 2015,44, 9349-9352

Chiral environment of catalytic sites in the chiral metal–organic frameworks

M. Lee, S. M. Shin, N. Jeong and P. K. Thallapally, Dalton Trans., 2015, 44, 9349 DOI: 10.1039/C5DT01322D

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