Issue 24, 2015
From the journal:

Dalton Transactions

A heterobimetallic [Mn II5Cu II5] nanowheel modulated by a flexible bis-oxamate type ligand†

Walace D. do Pim,ab   Érica N. de Faria,a   Willian X. C. Oliveira,a   Carlos B. Pinheiro,c   Wallace C. Nunes,d   Joan Cano,ef   Francesc Lloret,e   Miguel Julve,*e   Humberto O. Stumpfa  and  Cynthia L. M. Pereira*a  

* Corresponding authors

a Departamento de Química, Instituto de Ciências Exatas, Universidade Federal de Minas Gerais, Av. Antônio Carlos, 6627, Pampulha, BH, MG, Brazil
E-mail: cynthialopes@ufmg.br

b Departamento de Química, Centro Federal de Educação Tecnológica de Minas Gerais, Av. Amazonas, 5253, Belo Horizonte, MG, Brazil

c Departamento de Física, Instituto de Ciências Exatas, Universidade Federal de Minas Gerais, Av. Antônio Carlos, 6627, Pampulha, BH, MG, Brazil

d Instituto de Física, Universidade Federal Fluminense, Niterói, RJ, Brazil

e Instituto de Ciencia Molecular (ICMol), C/Catedrático José Beltrán, 46980 Paterna, Valencia, Spain
E-mail: Miguel.Julve@uv.es

f Fundació General de la Universitat de València (FGUV), Valencia, Spain

Abstract

The synthesis, crystal structure and preliminary magnetic characterization of a new heterobimetallic [MnII5CuII5] wheel containing a flexible bis-oxamate type ligand are described. This decanuclear compound exhibits a relatively strong intra-wheel antiferromagnetic interaction leading to a ground spin state S = 10.

Graphical abstract: A heterobimetallic [MnII5CuII5] nanowheel modulated by a flexible bis-oxamate type ligand

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Article information

DOI
https://doi.org/10.1039/C5DT00996K
Article type
Communication
Submitted
12 Mar 2015
Accepted
07 May 2015
First published
07 May 2015

Dalton Trans., 2015,44, 10939-10942

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A heterobimetallic [MnII5CuII5] nanowheel modulated by a flexible bis-oxamate type ligand

W. D. do Pim, É. N. de Faria, W. X. C. Oliveira, C. B. Pinheiro, W. C. Nunes, J. Cano, F. Lloret, M. Julve, H. O. Stumpf and C. L. M. Pereira, Dalton Trans., 2015, 44, 10939 DOI: 10.1039/C5DT00996K

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