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Issue 16, 2015
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B(C6F5)3 mediated arene hydrogenation/transannulation of para-methoxyanilines

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Abstract

The stoichiometric reaction of para-methoxyanilines and B(C6F5)3 under H2 results in reduction of the N-bound phenyl ring(s), and subsequent transannular ring closure with elimination of methanol, affording the respective 7-azabicyclo[2.2.1]heptane derivatives.

Graphical abstract: B(C6F5)3 mediated arene hydrogenation/transannulation of para-methoxyanilines

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Supplementary files

Article information


Submitted
04 Feb 2015
Accepted
09 Mar 2015
First published
13 Mar 2015

Dalton Trans., 2015,44, 7114-7117
Article type
Communication

B(C6F5)3 mediated arene hydrogenation/transannulation of para-methoxyanilines

L. E. Longobardi, T. Mahdi and D. W. Stephan, Dalton Trans., 2015, 44, 7114
DOI: 10.1039/C5DT00921A

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