Issue 9, 2015
From the journal:

Dalton Transactions

Novel electrochemi-/photo-luminescence of Ag3Cu5 heterometallic alkynyl clusters†

Yi Jiang,a   Wen-Jing Guo,a   De-Xian Kong,a   Yong-Tao Wang,a   Jin-Yun Wangc  and  Qiao-Hua Wei*abc  

* Corresponding authors

a Ministry of Education, Fujian Provincial Key Lab of Analysis and Detection for Food Safety, and Institute of Nanomedicine and Nanobiosensing, College of Chemistry, Fuzhou University, Fuzhou, China
E-mail: qhw76@fzu.edu.cn

b Beijing Synchrotron Radiation Laboratory, Institute of High Energy Physics, Beijing 100039, China

c State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter and Graduate School of CAS, Fuzhou, Fujian 350002, China

Abstract

Two windmill-like Ag3Cu5 alkynyl clusters were synthesized and characterized. They display novel PL and ECL properties, which could be modified by changing the substituent on the alkynyl ligands. According to the study of electrochemical behaviours, ECL behaviours and ECL emission spectra of the Ag3Cu5 clusters, a possible ECL mechanism was proposed.

Graphical abstract: Novel electrochemi-/photo-luminescence of Ag3Cu5 heterometallic alkynyl clusters

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Article information

DOI
https://doi.org/10.1039/C4DT03369H
Article type
Communication
Submitted
03 Nov 2014
Accepted
22 Dec 2014
First published
22 Dec 2014

Dalton Trans., 2015,44, 3941-3944

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Novel electrochemi-/photo-luminescence of Ag3Cu5 heterometallic alkynyl clusters

Y. Jiang, W. Guo, D. Kong, Y. Wang, J. Wang and Q. Wei, Dalton Trans., 2015, 44, 3941 DOI: 10.1039/C4DT03369H

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