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Issue 2, 2015
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In situ tetrazole templated chair-like decanuclear azido-cobalt(ii) SMM containing both tetra- and octa-hedral Co(ii) ions

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Abstract

An azido-bridged chair-like decanuclear cluster: [CoII10(bzp)8(Metz)2(N3)18]·4MeOH·3H2O (1, bzp = 2-benzoylpyridine and HMetz = 5-methyl-1H-tetrazole) was prepared with in situ tetrazolate anions as templates in a sealed system. 1 containing both octahedral and tetrahedral Co(II) ions exhibited slow relaxation of magnetization with an effective barrier of 26 K under an applied dc field of 1 kOe.

Graphical abstract: In situ tetrazole templated chair-like decanuclear azido-cobalt(ii) SMM containing both tetra- and octa-hedral Co(ii) ions

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Supplementary files

Article information


Submitted
17 Oct 2014
Accepted
05 Nov 2014
First published
10 Nov 2014

Dalton Trans., 2015,44, 480-483
Article type
Communication
Author version available

In situ tetrazole templated chair-like decanuclear azido-cobalt(II) SMM containing both tetra- and octa-hedral Co(II) ions

Y. Zhang, S. Gao and O. Sato, Dalton Trans., 2015, 44, 480
DOI: 10.1039/C4DT03211J

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