Issue 5, 2015

Synthesis and characterization of bimetallic metal–organic framework Cu–Ru-BTC with HKUST-1 structure

Abstract

The bimetallic metal–organic framework Cu–Ru-BTC with the stoichiometric formula Cu2.75Ru0.25(BTC)2·xH2O, which is isoreticular to HKUST-1, was successfully prepared in a direct synthesis using mild reaction conditions. The partial substitution of Cu2+ by Ru3+ centers in the paddlewheel structure and the absence of other Ru-containing phases was proven using X-ray absorption spectroscopy.

Graphical abstract: Synthesis and characterization of bimetallic metal–organic framework Cu–Ru-BTC with HKUST-1 structure

Supplementary files

Article information

Article type
Communication
Submitted
15 Aug 2014
Accepted
05 Dec 2014
First published
05 Dec 2014
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2015,44, 2052-2056

Synthesis and characterization of bimetallic metal–organic framework Cu–Ru-BTC with HKUST-1 structure

M. A. Gotthardt, R. Schoch, S. Wolf, M. Bauer and W. Kleist, Dalton Trans., 2015, 44, 2052 DOI: 10.1039/C4DT02491E

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements