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Issue 2, 2015
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Reductive dechlorination of BCl3 for efficient ammonia borane regeneration

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Abstract

This paper reports a complete ammonia borane (AB) regeneration process in which Bu3SnH was utilized as a reductant for the reductive dechlorination of BCl3, and Et2PhN was selected as a ‘helper ligand’ to generate Et2PhN·BH3, which gives rise to a high yield of AB by a base-exchange reaction at ambient temperature.

Graphical abstract: Reductive dechlorination of BCl3 for efficient ammonia borane regeneration

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Article information


Submitted
29 May 2014
Accepted
31 Oct 2014
First published
31 Oct 2014

Dalton Trans., 2015,44, 753-757
Article type
Paper

Reductive dechlorination of BCl3 for efficient ammonia borane regeneration

Y. Tan, L. Zhang, X. Chen and X. Yu, Dalton Trans., 2015, 44, 753
DOI: 10.1039/C4DT01592D

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