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Issue 43, 2014
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Ti7-containing, tetrahedral 36-tungsto-4-arsenate(III) [Ti6(TiO6)(AsW9O33)4]20−

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Abstract

We have prepared the Ti7-containing, tetrahedral 36-tungsto-4-arsenate(III) [Ti6(TiO6)(AsW9O33)4]20− (1) by a simple, one pot procedure. Polyanion 1 contains a novel Ti7-core, comprising a central TiO6 octahedron surrounded by six TiO5 square-pyramids, and capped by four {AsIIIW9} trilacunary fragments. The title polyanion is solution-stable, as shown by 183W NMR and mass spectrometry, and exhibits interesting biological properties.

Graphical abstract: Ti7-containing, tetrahedral 36-tungsto-4-arsenate(iii) [Ti6(TiO6)(AsW9O33)4]20−

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Publication details

The article was received on 16 Aug 2014, accepted on 01 Sep 2014 and first published on 02 Sep 2014


Article type: Communication
DOI: 10.1039/C4DT02494J
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Dalton Trans., 2014,43, 16143-16146
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    Ti7-containing, tetrahedral 36-tungsto-4-arsenate(III) [Ti6(TiO6)(AsW9O33)4]20−

    K. Wang, B. S. Bassil, Z. Lin, A. Haider, J. Cao, H. Stephan, K. Viehweger and U. Kortz, Dalton Trans., 2014, 43, 16143
    DOI: 10.1039/C4DT02494J

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