Issue 42, 2014
From the journal:

Dalton Transactions

Anion-controlled formation of an aminal-(bis)imine Fe(ii)-complex†

Chandan Giri,ab   Filip Topić,a   Prasenjit Mal*b  and  Kari Rissanen*a  

* Corresponding authors

a Department of Chemistry, Nanoscience Center, University of Jyväskylä, P.O. Box 35, FI-40014 Finland
E-mail: kari.t.rissanen@jyu.fi
Tel: +358-50-5623721

b School of Chemical Sciences, NISER Bhubaneswar, PO Sainik School, IOP Campus, Bhubaneswar, Odisha, India 751005
E-mail: pmal@niser.ac.in
Tel: +916742304073

Abstract

In the presence of triflate as the counter anion, 1,2-diaminobenzene and 2-formylpyridine self-sort with iron(II) to a low-spin [Fe(L1)](OTf)2 complex in which both aminal and imine moieties coexist simultaneously, while under similar conditions the chloride anion leads to a high-spin [Fe(L2)Cl2] complex.

Graphical abstract: Anion-controlled formation of an aminal-(bis)imine Fe(ii)-complex

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Article information

DOI
https://doi.org/10.1039/C4DT02180K
Article type
Communication
Submitted
18 Jul 2014
Accepted
21 Aug 2014
First published
27 Aug 2014

Dalton Trans., 2014,43, 15697-15699

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Anion-controlled formation of an aminal-(bis)imine Fe(II)-complex

C. Giri, F. Topić, P. Mal and K. Rissanen, Dalton Trans., 2014, 43, 15697 DOI: 10.1039/C4DT02180K

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