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Issue 44, 2014
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Synthesis, structures, and reactivity of the base-stabilized silanone molybdenum complexes

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Abstract

Base-stabilized silanone molybdenum complexes were synthesized by the oxygenation of the M[double bond, length as m-dash]Si bond in the silyl(silylene)molybdenum complex with 1 eq. of PNO in the presence of Lewis base L. The PNO-coordinated silanone complex (L = PNO) was converted to cis-[Cp*(OC)2Mo{OSiMes2(OSiMe3)}(PMe3)] in the presence of excess PMe3.

Graphical abstract: Synthesis, structures, and reactivity of the base-stabilized silanone molybdenum complexes

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Article information


Submitted
16 Jul 2014
Accepted
22 Sep 2014
First published
23 Sep 2014

Dalton Trans., 2014,43, 16610-16613
Article type
Communication
Author version available

Synthesis, structures, and reactivity of the base-stabilized silanone molybdenum complexes

T. Muraoka, K. Abe, H. Kimura, Y. Haga, K. Ueno and Y. Sunada, Dalton Trans., 2014, 43, 16610
DOI: 10.1039/C4DT02159B

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