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Issue 43, 2014
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Crystal transformation synthesis of a highly stable fluorescent 3D indium-tetranuclear {In42-OH)3} building block based metal organic framework through a dinuclear complex

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Abstract

A rare 3D tetranuclear {In42-OH)3} building block based MOF {[In4/32-OH)(2,6-pydc)(1,4-bda)0.5(H2O)]·2H2O}n (2) was obtained through a crystal transformation from a dimeric complex In3(2,6-pydc)3(1,4-bda)1.5(H2O)6 (1). With a 2D + 3D → 3D compact structure, 2 retains crystallinity in boiling water and organic solvents, exhibiting exceptional fluorescence quenching behaviour for the DMSO molecule.

Graphical abstract: Crystal transformation synthesis of a highly stable fluorescent 3D indium-tetranuclear {In4(μ2-OH)3} building block based metal organic framework through a dinuclear complex

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Publication details

The article was received on 07 Jul 2014, accepted on 25 Jul 2014 and first published on 28 Jul 2014


Article type: Communication
DOI: 10.1039/C4DT02045F
Dalton Trans., 2014,43, 16152-16155

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    Crystal transformation synthesis of a highly stable fluorescent 3D indium-tetranuclear {In42-OH)3} building block based metal organic framework through a dinuclear complex

    X. Wang, R. Fan, L. Qiang, P. Wang, Y. Yang and Y. Wang, Dalton Trans., 2014, 43, 16152
    DOI: 10.1039/C4DT02045F

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