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Issue 41, 2014
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Formation of bis(2-pyridylcarbonyl)aminate by oxidation of ethylbis(2-pyridylmethyl)amine on the trichloridoruthenium(iii) complex

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Abstract

Oxidation of the facial-type trichloridoruthenium(III) complex bearing ethylbis(2-pyridyl-methyl)amine (ebpma), fac-[RuIIICl3(ebpma)], with an equimolecular amount of (NH4)2[CeIV(NO3)6] in acetonitrile afforded a ligand-based oxidation product of an acetonitriledichloridoruthenium(III) complex having bis(2-pyridylcarbonyl)aminato (bpca), [RuIIICl2(NCCH3)(bpca)]. The complex changed into a trichloridoruthenium(III) complex by a reaction with hydrochloric acid and the triacetonitrileruthenium(II) complex by reduction with Zn in ethanol–acetonitrile. The bpca moiety showed interactions with cations such as protons.

Graphical abstract: Formation of bis(2-pyridylcarbonyl)aminate by oxidation of ethylbis(2-pyridylmethyl)amine on the trichloridoruthenium(iii) complex

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Publication details

The article was received on 20 Jun 2014, accepted on 19 Aug 2014 and first published on 04 Sep 2014


Article type: Paper
DOI: 10.1039/C4DT01842G
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Dalton Trans., 2014,43, 15391-15397

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    Formation of bis(2-pyridylcarbonyl)aminate by oxidation of ethylbis(2-pyridylmethyl)amine on the trichloridoruthenium(III) complex

    H. Nagao, N. Shimura and H. Yonezawa, Dalton Trans., 2014, 43, 15391
    DOI: 10.1039/C4DT01842G

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