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Issue 22, 2014

An unprecedented cyclometallated platinum(ii) complex incorporating a phosphinine co-ligand: synthesis and photoluminescence behaviour

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Abstract

The first luminescent cyclometallated platinum(II) complex bearing phosphinine co-ligands is reported. The long-lived luminescence, which it displays at 77 K, is assigned to a phosphinine-localised triplet excited state on the basis of electrochemical data and TD-DFT calculations.

Graphical abstract: An unprecedented cyclometallated platinum(ii) complex incorporating a phosphinine co-ligand: synthesis and photoluminescence behaviour

Supplementary files

Article information


Submitted
25 Feb 2014
Accepted
14 Mar 2014
First published
14 Mar 2014

Dalton Trans., 2014,43, 8162-8165
Article type
Communication
Author version available

An unprecedented cyclometallated platinum(II) complex incorporating a phosphinine co-ligand: synthesis and photoluminescence behaviour

J. Moussa, T. Cheminel, G. R. Freeman, L. Chamoreau, J. A. G. Williams and H. Amouri, Dalton Trans., 2014, 43, 8162 DOI: 10.1039/C4DT00589A

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