Issue 22, 2014
From the journal:

Dalton Transactions

An unprecedented cyclometallated platinum(ii) complex incorporating a phosphinine co-ligand: synthesis and photoluminescence behaviour†

Jamal Moussa,*a   Thomas Cheminel,a   Gemma R. Freeman,b   Lise-Marie Chamoreau,a   J. A. Gareth Williamsb  and  Hani Amouri*a  

* Corresponding authors

a UPMC Université Paris 06, Institut Parisien de Chimie Moléculaire (UMR 8232), 4 place Jussieu, 75252 Paris Cedex 05, France
E-mail: jamal.moussa@upmc.fr, hani.amouri@upmc.fr
Tel: (+33)1-44-27-30-83

b Department of Chemistry, Durham University, Durham, DH1 3LE, UK
E-mail: j.a.g.williams@durham.ac.uk

Abstract

The first luminescent cyclometallated platinum(II) complex bearing phosphinine co-ligands is reported. The long-lived luminescence, which it displays at 77 K, is assigned to a phosphinine-localised triplet excited state on the basis of electrochemical data and TD-DFT calculations.

Graphical abstract: An unprecedented cyclometallated platinum(ii) complex incorporating a phosphinine co-ligand: synthesis and photoluminescence behaviour

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Article information

DOI
https://doi.org/10.1039/C4DT00589A
Article type
Communication
Submitted
25 Feb 2014
Accepted
14 Mar 2014
First published
14 Mar 2014

Dalton Trans., 2014,43, 8162-8165

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An unprecedented cyclometallated platinum(II) complex incorporating a phosphinine co-ligand: synthesis and photoluminescence behaviour

J. Moussa, T. Cheminel, G. R. Freeman, L. Chamoreau, J. A. G. Williams and H. Amouri, Dalton Trans., 2014, 43, 8162 DOI: 10.1039/C4DT00589A

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