Issue 24, 2014
From the journal:

Dalton Transactions

The dinitrosyliron complex [Fe4(μ3-S)2(μ2-NO)2(NO)6]2− containing bridging nitroxyls: 15N (NO) NMR analysis of the bridging and terminal NO-coordinate ligands†

Shih-Wey Yeh,a   Chih-Chin Tsoua  and  Wen-Feng Liaw*a  

* Corresponding authors

a Department of Chemistry, National Tsing Hua University, Hsinchu 30013, Taiwan
E-mail: wfliaw@mx.nthu.edu.tw
Fax: +886-3-5711082
Tel: +886-3-5715131 ext 35663

Abstract

The fluxional terminal and semibridging NO-coordinate ligands of DNIC [Fe4(μ3-S)2(μ2-NO)2(NO)6]2−, a precursor of Roussin's black salt (RBS), are characterized by IR ν(NO), 15N (NO) NMR and single-crystal X-ray diffraction.

Graphical abstract: The dinitrosyliron complex [Fe4(μ3-S)2(μ2-NO)2(NO)6]2− containing bridging nitroxyls: 15N (NO) NMR analysis of the bridging and terminal NO-coordinate ligands

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Article information

DOI
https://doi.org/10.1039/C4DT00450G
Article type
Communication
Submitted
14 Feb 2014
Accepted
23 Apr 2014
First published
23 Apr 2014

Dalton Trans., 2014,43, 9022-9025

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The dinitrosyliron complex [Fe4(μ3-S)2(μ2-NO)2(NO)6]2− containing bridging nitroxyls: 15N (NO) NMR analysis of the bridging and terminal NO-coordinate ligands

S. Yeh, C. Tsou and W. Liaw, Dalton Trans., 2014, 43, 9022 DOI: 10.1039/C4DT00450G

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