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Issue 25, 2014
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Unveiling the mechanism of selective gate-driven diffusion of CO2 over N2 in MFU-4 metal–organic framework

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Abstract

The metal–organic framework MFU-4 shows preferential adsorption of CO2 over N2. This cannot be explained in terms of pore size only. Computational modelling suggests that the unique structure and flexibility of its small 8Cl-cube pore shows a unique gate-diffusion behaviour with different responses to CO2 and N2.

Graphical abstract: Unveiling the mechanism of selective gate-driven diffusion of CO2 over N2 in MFU-4 metal–organic framework

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Publication details

The article was received on 04 Feb 2014, accepted on 07 May 2014 and first published on 16 May 2014


Article type: Paper
DOI: 10.1039/C4DT00365A
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Dalton Trans., 2014,43, 9612-9619
  • Open access: Creative Commons BY-NC license
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    Unveiling the mechanism of selective gate-driven diffusion of CO2 over N2 in MFU-4 metal–organic framework

    G. Sastre, J. van den Bergh, F. Kapteijn, D. Denysenko and D. Volkmer, Dalton Trans., 2014, 43, 9612
    DOI: 10.1039/C4DT00365A

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