Jump to main content
Jump to site search

Issue 25, 2014
Previous Article Next Article

A spin-crossover complex based on a 2,6-bis(pyrazol-1-yl)pyridine (1-bpp) ligand functionalized with a carboxylate group

Author affiliations

Abstract

Combining Fe(II) with the carboxylate-functionalized 2,6-bis(pyrazol-1-yl)pyridine (bppCOOH) ligand results in the spin-crossover compound [Fe(bppCOOH)2](ClO4)2 which shows an abrupt spin transition with a T1/2 of ca. 380 K and a TLIESST of 60 K due to the presence of a hydrogen-bonded linear network of complexes.

Graphical abstract: A spin-crossover complex based on a 2,6-bis(pyrazol-1-yl)pyridine (1-bpp) ligand functionalized with a carboxylate group

Back to tab navigation

Supplementary files

Additions and corrections

Publication details

The article was received on 30 Jan 2014, accepted on 13 Mar 2014 and first published on 17 Mar 2014


Article type: Communication
DOI: 10.1039/C4DT00327F
Author version
available:
Download author version (PDF)
Citation: Dalton Trans., 2014,43, 9406-9409

  •   Request permissions

    A spin-crossover complex based on a 2,6-bis(pyrazol-1-yl)pyridine (1-bpp) ligand functionalized with a carboxylate group

    A. Abhervé, M. Clemente-León, E. Coronado, C. J. Gómez-García and M. López-Jordà, Dalton Trans., 2014, 43, 9406
    DOI: 10.1039/C4DT00327F

Search articles by author

Spotlight

Advertisements