[(Me)2NH2][BiGeS4]: the first organically directed bismuth thiogermanate with Rb+ ion exchange property

Mei-Ling Feng; Xing-Hui Qi; Bo Zhang; Xiao-Ying Huang

doi:10.1039/C4DT00173G

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[(Me)₂NH₂][BiGeS₄]: the first organically directed bismuth thiogermanate with Rb⁺ ion exchange property†

Mei-Ling Feng,^a Xing-Hui Qi,^ab Bo Zhang^ac and Xiao-Ying Huang*^a

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* Corresponding authors

^a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China
E-mail: xyhuang@fjirsm.ac.cn
Fax: +86 591 83793727

^b Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, P. R. China

^c Graduate University of the Chinese Academy of Sciences, Beijing 100049, P. R. China

Abstract

The first organically directed bismuth thiogermanate, namely [(Me)₂NH₂][BiGeS₄] (1), has been solvothermally synthesized and characterized. The structure features a two-dimensional anionic network of [BiGeS₄]_nⁿ⁻, with dimethylammonium as a counterion and a structure-directing agent. 1 is able to undergo ion exchange with Rb⁺ ions.

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Article information

DOI: https://doi.org/10.1039/C4DT00173G
Article type: Communication
Submitted: 17 Jan 2014
Accepted: 07 Mar 2014
First published: 10 Mar 2014

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Dalton Trans., 2014,43, 8184-8187

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[(Me)₂NH₂][BiGeS₄]: the first organically directed bismuth thiogermanate with Rb⁺ ion exchange property

M. Feng, X. Qi, B. Zhang and X. Huang, Dalton Trans., 2014, 43, 8184 DOI: 10.1039/C4DT00173G

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Dalton Transactions