Issue 22, 2014
From the journal:

Dalton Transactions

Tuning of gate adsorption: modification of a flexible metal–organic framework by secondary organic ligands†

Atsushi Kondo,*a   Takuro Fujiia  and  Kazuyuki Maeda*a  

* Corresponding authors

a Department of Applied Chemistry, Faculty of Engineering, Tokyo University of Agriculture and Technology, 2-24-16 Naka-cho, Koganei, Tokyo 184-8588, Japan
E-mail: kondoa@cc.tuat.ac.jp, k-maeda@cc.tuat.ac.jp
Fax: Tel: +81 42 388 7040

Abstract

For realizing selective adsorption of targeted molecules, a flexible metal–organic framework (MOF) was modified with monodentate secondary ligands. Although the modified MOF retains CO2 adsorptivities with a vertical adsorption uptake, the material also shows gate adsorptivities of a specific gas molecule that the pristine MOF does not adsorb.

Graphical abstract: Tuning of gate adsorption: modification of a flexible metal–organic framework by secondary organic ligands

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Article information

DOI
https://doi.org/10.1039/C4DT00116H
Article type
Communication
Submitted
14 Jan 2014
Accepted
12 Mar 2014
First published
12 Mar 2014

Dalton Trans., 2014,43, 8174-8177

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Tuning of gate adsorption: modification of a flexible metal–organic framework by secondary organic ligands

A. Kondo, T. Fujii and K. Maeda, Dalton Trans., 2014, 43, 8174 DOI: 10.1039/C4DT00116H

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