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Issue 17, 2014
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New perspectives in hydrogen storage based on RCH2NH2/RCN couples

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Abstract

A recent breakthrough in primary amine dehydrogenation by an oxidant-free process, and without any hydrogen acceptor, opens the possibility for RCH2NH2/RCN couples to be considered as potential hydrogen energy carriers. Both hydrogenation and dehydrogenation processes can be catalysed by ruthenium complexes under rather mild conditions. This emerging exciting approach could be the starting point for the development of valuable economical systems.

Graphical abstract: New perspectives in hydrogen storage based on RCH2NH2/RCN couples

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Article information


Submitted
20 Dec 2013
Accepted
07 Feb 2014
First published
17 Mar 2014

Dalton Trans., 2014,43, 6283-6286
Article type
Frontier
Author version available

New perspectives in hydrogen storage based on RCH2NH2/RCN couples

M. Grellier and S. Sabo-Etienne, Dalton Trans., 2014, 43, 6283
DOI: 10.1039/C3DT53583E

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