Issue 3, 2014
From the journal:

Dalton Transactions

The supramolecular interaction mediated chiral 1D cyanide-bridged metamagnet: synthesis, crystal structures and magnetic properties†

Daopeng Zhang,*ab   Yongzhong Bian,b   Jie Qin,a   Ping Wanga  and  Xia Chena  

* Corresponding authors

a College of Chemical Engineering, Shandong University of Technology, Zibo 255049, China
E-mail: dpzhang@sdut.edu.cn

b Department of Chemistry, University of Science and Technology Beijing, Beijing 100083, China

Abstract

Two cyanide-bridged enantiopure one-dimensional single chain complexes, [Mn((R,R)-Salcy)Fe(pcq)(CN)3]2n·1.5nDMF (1) and [Mn((S,S)-Salcy)Fe(pcq)(CN)3]2n·1.5nDMF (2), have been synthesized and structurally characterized. Systematically magnetic investigations show the antiferromagnetic coupling between the cyanide-bridged Mn(III)–Fe(III) centers and the interesting metamagnetic behavior at about 5.0 K resulted from the intermolecular π–π interaction.

Graphical abstract: The supramolecular interaction mediated chiral 1D cyanide-bridged metamagnet: synthesis, crystal structures and magnetic properties

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Article information

DOI
https://doi.org/10.1039/C3DT52996G
Article type
Communication
Submitted
23 Oct 2013
Accepted
08 Nov 2013
First published
11 Nov 2013

Dalton Trans., 2014,43, 945-949

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The supramolecular interaction mediated chiral 1D cyanide-bridged metamagnet: synthesis, crystal structures and magnetic properties

D. Zhang, Y. Bian, J. Qin, P. Wang and X. Chen, Dalton Trans., 2014, 43, 945 DOI: 10.1039/C3DT52996G

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