Issue 8, 2014
From the journal:

Dalton Transactions

A semi-flexible aminotriazine-based bis-methylpyridine ligand for the design of nickel(ii) spin clusters†

Yen-Wen Tzeng,a   Chang-Jui Lin,a   Motohiro Nakano,b   Chen-I Yang,*a   Wun-Long Wanc  and  Long-Li Lai*c  

* Corresponding authors

a Department of Chemistry, Tunghai University, Taichung 407, Taiwan
E-mail: ciyang@thu.edu.tw
Fax: +886-4-23590426

b Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, Japan

c Department of Applied Chemistry, National Chi Nan University, Nantou 545, Taiwan
E-mail: lilai@ncnu.edu.tw

Abstract

The self-assembly of a semi-flexible aminotriazine-based bis-methylpyridine ligand, N2,N2-dibenzyl-N4,N6-di(pyridylmethyl)-1,3,5-triazine-2,4,6-triamine (H2L), with NiCl2 and NiBr2 afforded two new nickel(II) clusters, (H2NMe2)2[Ni5(OH)2(H2L)2Cl10] (1) and [Ni6(OH)2(H2L)2Br10(THF)2] (2) showing a high spin ground state of S = 3.

Graphical abstract: A semi-flexible aminotriazine-based bis-methylpyridine ligand for the design of nickel(ii) spin clusters

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Article information

DOI
https://doi.org/10.1039/C3DT52903G
Article type
Communication
Submitted
15 Oct 2013
Accepted
30 Oct 2013
First published
05 Nov 2013
This article is Open Access
Creative Commons BY license

Dalton Trans., 2014,43, 3044-3047

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A semi-flexible aminotriazine-based bis-methylpyridine ligand for the design of nickel(II) spin clusters

Y. Tzeng, C. Lin, M. Nakano, C. Yang, W. Wan and L. Lai, Dalton Trans., 2014, 43, 3044 DOI: 10.1039/C3DT52903G

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