Issue 13, 2014

Nucleophilic addition of carborane anion to Ir, Rh-coordinated Cp* ring: C–C bond formation accompanied by reduction of metal center

Abstract

Reaction of carboranyl anion or its thiolate derivative with a fully-substituted Cp*-based group 9 (Ir, Rh) metal complex affords respectively a C–C bond formation complex and a salt metathesis product. This example represents the first nucleophilic addition attempt in the area of M-Cp* chemistry.

Graphical abstract: Nucleophilic addition of carborane anion to Ir, Rh-coordinated Cp* ring: C–C bond formation accompanied by reduction of metal center

  • This article is part of the themed collection: Carboranes

Supplementary files

Article information

Article type
Communication
Submitted
14 Jul 2013
Accepted
23 Jul 2013
First published
23 Jul 2013

Dalton Trans., 2014,43, 4938-4940

Nucleophilic addition of carborane anion to Ir, Rh-coordinated Cp* ring: C–C bond formation accompanied by reduction of metal center

Z. Yao, Y. Lin, B. Xu and G. Jin, Dalton Trans., 2014, 43, 4938 DOI: 10.1039/C3DT51906F

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