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Issue 48, 2013
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Hexa-substituted polyoxometalates made of trivacant Dawson {P2W15} fragments and {Ni6} clusters under hydrothermal conditions

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Abstract

Three novel polyoxometalates (POMs) containing [Ni63-OH)3]9− and [P2W15O56]12− units were first made, showing the first hexa-nuclearity transition-metal substituted POMs (TMSPs) based on monomeric lacunary Dawson fragments, which further indicates that the hydrothermal technique can offer an effective way for making new TMSPs through lacunary POM fragments incorporated with high-nuclear TM clusters.

Graphical abstract: Hexa-substituted polyoxometalates made of trivacant Dawson {P2W15} fragments and {Ni6} clusters under hydrothermal conditions

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Article information


Submitted
03 Jul 2013
Accepted
07 Oct 2013
First published
08 Oct 2013

Dalton Trans., 2013,42, 16676-16679
Article type
Communication

Hexa-substituted polyoxometalates made of trivacant Dawson {P2W15} fragments and {Ni6} clusters under hydrothermal conditions

Y. Liu, C. Fu, S. Zheng, J. Zhao and G. Yang, Dalton Trans., 2013, 42, 16676
DOI: 10.1039/C3DT51786A

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