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Issue 34, 2013
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Low temperature red luminescence of a fluorinated Mn-doped zinc selenite

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Abstract

M2(SeO3)F2 (M = Zn (1), Mn (2)) stoichiometric phases together with the Zn2−xMnx(SeO3)F2 compound doped at various concentrations (x = 0.002–0.2) were synthesized by employing mild hydrothermal conditions. These compounds have been characterized by scanning electron microscopy (SEM), Rietveld refinement of the X-ray powder diffraction patterns, ICP-Q-MS, thermogravimetric and thermodiffractometric analyses, and IR, UV/vis and electron paramagnetic resonance (EPR) spectroscopies. Compounds 1 and 2 crystallize in the orthorhombic Pnma space group with lattice parameters: a = 7.27903(4), b = 10.05232(6) and c = 5.26954(3) Å for the zinc species and a = 7.50848(9), b = 10.3501(12) and c = 5.47697(6) Å for the manganese phase, with Z = 4. The crystal structures of these compounds are isotypic and are built up from a 3D framework constructed by (010) sheets of [MO3F3] octahedra linked up by [SeO3] building units. Luminescence measurements of Mn2(SeO3)F2 were performed at different temperatures between 10 and 150 K. At 10 K, the emission spectrum consists of a broad band peaked at around 660 nm related to the 4T1g6A1g transition in octahedrically coordinated Mn2+. Moreover, the influence of temperatures up to 295 K and the Mn concentration on the luminescent properties of the Zn2−xMnx(SeO3)F2 system were systematically studied. Magnetic measurements of 2 show antiferromagnetic coupling as the major interactions exhibiting a spin canting at low temperature.

Graphical abstract: Low temperature red luminescence of a fluorinated Mn-doped zinc selenite

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Supplementary files

Article information


Submitted
09 May 2013
Accepted
01 Jul 2013
First published
01 Jul 2013

Dalton Trans., 2013,42, 12481-12494
Article type
Paper

Low temperature red luminescence of a fluorinated Mn-doped zinc selenite

J. Orive, R. Balda, J. Fernández, L. Lezama and M. I. Arriortua, Dalton Trans., 2013, 42, 12481
DOI: 10.1039/C3DT51224J

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