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Issue 25, 2013
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Regio- and stereospecific living polymerization and copolymerization of (E)-1,3-pentadiene with 1,3-butadiene by half-sandwich scandium catalysts

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Abstract

The living isospecific-cis-1,4-polymerization and block-copolymerization of (E)-1,3-pentadiene with 1,3-butadiene have been achieved for the first time by using cationic half-sandwich scandium catalysts.

Graphical abstract: Regio- and stereospecific living polymerization and copolymerization of (E)-1,3-pentadiene with 1,3-butadiene by half-sandwich scandium catalysts

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Submitted
05 Feb 2013
Accepted
04 Mar 2013
First published
04 Mar 2013

Dalton Trans., 2013,42, 9030-9032
Article type
Communication

Regio- and stereospecific living polymerization and copolymerization of (E)-1,3-pentadiene with 1,3-butadiene by half-sandwich scandium catalysts

K. Nishii, X. Kang, M. Nishiura, Y. Luo and Z. Hou, Dalton Trans., 2013, 42, 9030
DOI: 10.1039/C3DT50357G

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