Issue 7, 2013
From the journal:

Dalton Transactions

Redox-switchable tetra-copper assembly of N,N-, N,O-phenolate-phenanthroimidazolate bridging ligands†

Jenny-Lee Mathias,a   Himanshu Arora,a   Ronit Lavi,a   Hervé Vezin,b   Dmitry Yufit,c   Maylis Orio,b   Núria Aliaga-Alcaded  and  Laurent Benisvy*a  

* Corresponding authors

a Department of Chemistry, Bar-Ilan University, Ramat Gan, Israel
E-mail: benisvl@mail.biu.ac.il
Fax: +972-3-7384053
Tel: +972-3-7384599

b Laboratoire de Spectrochimie Infrarouge et Raman, CNRS LASIR-UMR 8516, Bat C4 F-59655 Villeneuve d'Ascq Cedex, France

c Department of Chemistry, University of Durham, South Road, Durham, UK

d ICREA – Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus de la UAB, 08193 Bellaterra, Spain

Abstract

A redox-active dianionic N,O-phenolate-imidazolate/N,N-phenanthroline bridging ligand is used to form unique square-like neutral tetra-Cu(II) assemblies, the structural, magnetic, electronic and redox properties of which are herein described.

Graphical abstract: Redox-switchable tetra-copper assembly of N,N-, N,O-phenolate-phenanthroimidazolate bridging ligands

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Article information

DOI
https://doi.org/10.1039/C2DT32585C
Article type
Communication
Submitted
29 Oct 2012
Accepted
19 Dec 2012
First published
19 Dec 2012

Dalton Trans., 2013,42, 2358-2361

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Redox-switchable tetra-copper assembly of N,N-, N,O-phenolate-phenanthroimidazolate bridging ligands

J. Mathias, H. Arora, R. Lavi, H. Vezin, D. Yufit, M. Orio, N. Aliaga-Alcade and L. Benisvy, Dalton Trans., 2013, 42, 2358 DOI: 10.1039/C2DT32585C

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