Issue 18, 2013
From the journal:

Dalton Transactions

Stoichiometric and catalytic reactions of LiAlH4 with Me2NHBH3†

Robert J. Less,*a   Hayley R. Simmonds,a   Sarah B. J. Danea  and  Dominic S. Wright*a  

* Corresponding authors

a Chemistry Department, Cambridge University, Lensfield Road, Cambridge CB2 1EW, UK
E-mail: dsw1000@cam.ac.uk
Fax: +44 (0)1223 336362
Tel: +44 (0)1223 763122

Abstract

Structural and in situ NMR spectroscopic studies show that N–H deprotonation, B–N bond cleavage and B–N bond formation can occur in the stoichiometric and catalytic reactions of LiAlH4 with Me2NHBH3.

Graphical abstract: Stoichiometric and catalytic reactions of LiAlH4 with Me2NHBH3

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Article information

DOI
https://doi.org/10.1039/C2DT32569A
Article type
Paper
Submitted
26 Oct 2012
Accepted
13 Dec 2012
First published
18 Dec 2012

Dalton Trans., 2013,42, 6337-6343

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Stoichiometric and catalytic reactions of LiAlH4 with Me2NHBH3

R. J. Less, H. R. Simmonds, S. B. J. Dane and D. S. Wright, Dalton Trans., 2013, 42, 6337 DOI: 10.1039/C2DT32569A

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