Issue 7, 2013
From the journal:

Dalton Transactions

Position-selective intramolecular aromatic C–H bond activation of 1,2,3-triazol-5-ylidene (tzNHC) ligands in (p-cymene)ruthenium(ii) complexes†

Kenichi Ogata,a   Sayuri Inomataa  and  Shin-ichi Fukuzawa*a  

* Corresponding authors

a Department of Applied Chemistry, Institute of Science and Engineering, Chuo University, 1-13-27 Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan
E-mail: orgsynth@kc.chuo-u.ac.jp
Fax: +81-3-3817-1895
Tel: +81-3-3817-1916

Abstract

A series of 1,2,3-triazol-5-ylidene (tzNHC) complexes of a (p-cymene)ruthenium system was synthesized. The reactivity of the N-bonded and C-bonded aryl groups in the tzNHC ligand was found to be significantly different with respect to intramolecular aromatic C–H bond activation.

Graphical abstract: Position-selective intramolecular aromatic C–H bond activation of 1,2,3-triazol-5-ylidene (tzNHC) ligands in (p-cymene)ruthenium(ii) complexes

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Article information

DOI
https://doi.org/10.1039/C2DT32368K
Article type
Communication
Submitted
06 Oct 2012
Accepted
30 Nov 2012
First published
30 Nov 2012

Dalton Trans., 2013,42, 2362-2365

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Position-selective intramolecular aromatic C–H bond activation of 1,2,3-triazol-5-ylidene (tzNHC) ligands in (p-cymene)ruthenium(II) complexes

K. Ogata, S. Inomata and S. Fukuzawa, Dalton Trans., 2013, 42, 2362 DOI: 10.1039/C2DT32368K

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