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Issue 44, 2012
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Single-ion magnet behaviour in [U(TpMe2)2I]

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Abstract

[U(TpMe2)2I] exhibits at low temperatures single molecule magnet (SMM) behaviour comparable to its bipyridine derivative and related single ion U(III) complexes recently reported as SMMs. The trend of variation of the energy barrier for the magnetic relaxation in these compounds is well reproduced by quantum chemistry calculations.

Graphical abstract: Single-ion magnet behaviour in [U(TpMe2)2I]

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Article information


Submitted
01 Jul 2012
Accepted
26 Jul 2012
First published
30 Jul 2012

Dalton Trans., 2012,41, 13568-13571
Article type
Communication

Single-ion magnet behaviour in [U(TpMe2)2I]

J. T. Coutinho, M. A. Antunes, L. C. J. Pereira, H. Bolvin, J. Marçalo, M. Mazzanti and M. Almeida, Dalton Trans., 2012, 41, 13568
DOI: 10.1039/C2DT31421E

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