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Issue 44, 2012
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Slow magnetic relaxation in a 4,2-ribbon like FeIII2CoII heterobimetallic chain

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Abstract

The reaction of Co(NO3)2·6H2O and 3-benzoylpyridine with the low-spin iron(III) complex, H[FeIII(phen)(CN)4], in methanol gives rise to a cyanide-bridged heterobimetallic chain [{FeIII(phen)(CN)4}2CoII(3-bpe)2] (1) that exhibits intrachain ferromagnetic coupling and slow double magnetic relaxation.

Graphical abstract: Slow magnetic relaxation in a 4,2-ribbon like FeIII2CoII heterobimetallic chain

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Article information


Submitted
31 May 2012
Accepted
24 Sep 2012
First published
26 Sep 2012

Dalton Trans., 2012,41, 13575-13577
Article type
Communication

Slow magnetic relaxation in a 4,2-ribbon like FeIII2CoII heterobimetallic chain

S. Kang, S. Kanegawa and O. Sato, Dalton Trans., 2012, 41, 13575
DOI: 10.1039/C2DT31168B

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