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Issue 33, 2012
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Crystallization of a Keplerate-type polyoxometalate into a superposed kagome-lattice with huge channels

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Abstract

Crystal structures of two Sr2+ salts of the Keplerate-type polyoxometalate, [MoVI72MoV60O372(CH3COO)30(H2O)72]42−, have been determined by single crystal X-ray diffraction. One compound exhibits a superposed kagome-lattice with huge channels whose diameters measure approximately 3.0 nm, while the arrangement of the Keplerate anions in the other compound approximates to a distorted cubic close packing.

Graphical abstract: Crystallization of a Keplerate-type polyoxometalate into a superposed kagome-lattice with huge channels

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Publication details

The article was received on 13 Mar 2012, accepted on 17 Apr 2012 and first published on 27 Apr 2012


Article type: Communication
DOI: 10.1039/C2DT30582H
Dalton Trans., 2012,41, 9846-9848

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    Crystallization of a Keplerate-type polyoxometalate into a superposed kagome-lattice with huge channels

    M. Saito and T. Ozeki, Dalton Trans., 2012, 41, 9846
    DOI: 10.1039/C2DT30582H

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