Issue 26, 2012
From the journal:

Dalton Transactions

Lanthanide(iii) 2-naphthoxide complexes stabilized by interligand non-covalent interactions†

Jessica R. Levin,a   Jun Gu,a   Patrick J. Carrolla  and  Eric J. Schelter*a  

* Corresponding authors

a P. Roy and Diana T. Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104, USA
E-mail: schelter@sas.upenn.edu
Fax: (+1) 215-573-2112
Tel: (+1) 215-898-8633

Abstract

Lithium–lanthanide-2-naphthoxide complexes are found to have solvent dependent solution structures and related monomeric/dimeric solid state structures. The incorporation of tetramethylguanidium cations into lanthanide 2-naphthoxide complexes stabilizes a complex structure both in solution and the solid state through bridging hydrogen bonds between the 2-naphthoxide ligands.

Graphical abstract: Lanthanide(iii) 2-naphthoxide complexes stabilized by interligand non-covalent interactions

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Article information

DOI
https://doi.org/10.1039/C2DT30445G
Article type
Communication
Submitted
24 Feb 2012
Accepted
01 May 2012
First published
10 May 2012

Dalton Trans., 2012,41, 7870-7872

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Lanthanide(III) 2-naphthoxide complexes stabilized by interligand non-covalent interactions

J. R. Levin, J. Gu, P. J. Carroll and E. J. Schelter, Dalton Trans., 2012, 41, 7870 DOI: 10.1039/C2DT30445G

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