Jump to main content
Jump to site search

Issue 24, 2012
Previous Article Next Article

Doubly phenoxo–hydroxo-bridged dicopper(ii) complexes: individual contributions of the bridges to antiferromagnetic coupling based on two related biomimetic models for catechol oxidases

Author affiliations

Abstract

This paper describes the synthesis, structure and spectroscopic and magnetic properties of two (μ-phenoxo)(μ-hydroxo)dicopper(II) complexes (1 and 2) which contain similar N,O-donor atoms but with distinct coordination arrangements around the CuII centers. Structural and magnetic studies of 1 and 2 allowed us to evaluate, for the first time, the individual contributions of the {Cu(μ-phenoxo)Cu} and {Cu(μ-hydroxo)Cu} structural units to the antiferromagnetic coupling between the CuII centers in these complexes.

Graphical abstract: Doubly phenoxo–hydroxo-bridged dicopper(ii) complexes: individual contributions of the bridges to antiferromagnetic coupling based on two related biomimetic models for catechol oxidases

Back to tab navigation

Supplementary files

Article information


Submitted
22 Feb 2012
Accepted
26 Apr 2012
First published
26 Apr 2012

Dalton Trans., 2012,41, 7196-7200
Article type
Communication

Doubly phenoxo–hydroxo-bridged dicopper(II) complexes: individual contributions of the bridges to antiferromagnetic coupling based on two related biomimetic models for catechol oxidases

N. A. Rey, A. Neves, A. J. Bortoluzzi, W. Haase and Z. Tomkowicz, Dalton Trans., 2012, 41, 7196
DOI: 10.1039/C2DT30419H

Social activity

Search articles by author

Spotlight

Advertisements