Lithium phenolates with a hexagonal-prismatic Li6O6 core isolated via a cage-shaped tripodal ligands system: crystal structures and their behavior in solution

Hideto Nakajima; Makoto Yasuda; Akio Baba

doi:10.1039/C2DT30266G

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Lithium phenolates with a hexagonal-prismatic Li₆O₆ core isolated via a cage-shaped tripodal ligands system: crystal structures and their behavior in solution†

Hideto Nakajima,^a Makoto Yasuda*^a and Akio Baba*^a

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* Corresponding authors

^a Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan
E-mail: yasuda@chem.eng.osaka-u.ac.jp, baba@chem.eng.osaka-u.ac.jp
Fax: (+81) 6-6879-7387
Tel: (+81) 6-6879-7386

Abstract

Stable hexanuclear lithium phenolate bearing a cage-shaped tripodal ligand was isolated, which had a hexagonal-prismatic Li₆O₆ core at room temperature, because of the hard mobility of the ligand and its reduction of the problematic steric repulsion. The properties of the lithium phenolates were analyzed by X-ray crystallography and NMR spectroscopy.

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Article information

DOI: https://doi.org/10.1039/C2DT30266G
Article type: Communication
Submitted: 06 Feb 2012
Accepted: 02 Apr 2012
First published: 03 Apr 2012

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Dalton Trans., 2012,41, 6602-6606

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Lithium phenolates with a hexagonal-prismatic Li₆O₆ core isolated via a cage-shaped tripodal ligands system: crystal structures and their behavior in solution

H. Nakajima, M. Yasuda and A. Baba, Dalton Trans., 2012, 41, 6602 DOI: 10.1039/C2DT30266G

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Dalton Transactions