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Issue 26, 2012
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One-electron Ni(ii)/(i) redox couple: potential role in hydrogen activation and production

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Abstract

The three-coordinate Ni(I) complex Ni(Cl)(P2), where P2 is the diphosphine iPrDPDBFphos, reacts with the acids HCl·(dioxane) and 2,6-lutidinium chloride to generate Ni(H)(Cl)(P2) and Ni(Cl)2(P2). Photolysis of the Ni(H)(X)(P2) (for X = Cl, Br) results in formation of H2 and the Ni(I) halide. This reaction also proceeds in reverse when heated.

Graphical abstract: One-electron Ni(ii)/(i) redox couple: potential role in hydrogen activation and production

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Supplementary files

Article information


Submitted
24 Jan 2012
Accepted
16 Apr 2012
First published
27 Apr 2012

Dalton Trans., 2012,41, 7862-7865
Article type
Communication

One-electron Ni(II)/(I) redox couple: potential role in hydrogen activation and production

S. J. Tereniak, E. E. Marlier and C. C. Lu, Dalton Trans., 2012, 41, 7862
DOI: 10.1039/C2DT30176H

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