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Issue 26, 2012
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Complexes of Cu(i) supported by a tris(ketimine) tripod

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Abstract

Arylation of tris(2-benzylnitrile)amine with PhLi, followed by aqueous work-up, results in the formation of a tripodal tris(ketimine) scaffold, N(ArCNHPh)3. N(ArCNHPh)3 readily coordinates a number of CuI salts, generating complexes that exhibit trigonal pyramidal geometries in the solid-state.

Graphical abstract: Complexes of Cu(i) supported by a tris(ketimine) tripod

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Article information


Submitted
15 Jan 2012
Accepted
19 Mar 2012
First published
23 Mar 2012

Dalton Trans., 2012,41, 7859-7861
Article type
Communication

Complexes of Cu(I) supported by a tris(ketimine) tripod

J. J. Scepaniak, G. Wu and T. W. Hayton, Dalton Trans., 2012, 41, 7859
DOI: 10.1039/C2DT30101F

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