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Issue 26, 2012
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Utilizing a copper MOF as a reagent in a solvent mediated reaction to form a topologically distinct MOF†

Christopher R. Murdock,a   Zheng Lua  and  David M. Jenkins*a  
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* Corresponding authors

a Department of Chemistry, The University of Tennessee, Knoxville, Tennessee 37996-1600, USA
E-mail: jenkins@ion.chem.utk.edu
Tel: +1(865)974-8591

Abstract

Employing a semi-rigid di-1,2,4-triazole ligand leads to the formation of new MOFs [Cu4(L)4(SO4)4]·4[Cu(H2O)6(SO4)] (3) and [Cu6(L)3(SO4)5(OH)2(H2O)6]·13H2O (4). The frameworks can be synthesized independently, but a reaction occurs in water wherein kinetic product 3 is used as a reagent to synthesize the topologically distinct thermodynamic product 4.

Graphical abstract: Utilizing a copper MOF as a reagent in a solvent mediated reaction to form a topologically distinct MOF

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Article information

https://doi.org/10.1039/C2DT30078H
Submitted
11 Jan 2012
Accepted
05 Mar 2012
First published
15 Mar 2012
Dalton Trans., 2012,41, 7839-7841
Article type
Communication
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Utilizing a copper MOF as a reagent in a solvent mediated reaction to form a topologically distinct MOF

C. R. Murdock, Z. Lu and D. M. Jenkins, Dalton Trans., 2012, 41, 7839
DOI: 10.1039/C2DT30078H

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