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Issue 7, 2012
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Ionic liquid mediated routes to polydentate oxygen-donor adducts of cerium(III) bromide

Kalyan V. Vasudevan,a  Nickolaus A. Smith,b  Brian L. Scott,c  Bryan L. Bennett,b  Ross E. Muenchausenb  and  John C. Gordon*a 
Author affiliations

* Corresponding authors

a Chemistry Division (C-IIAC), Los Alamos National Laboratory, Los Alamos, USA
E-mail: jgordon@lanl.gov
Tel: 505-665-6962

b Materials, Science and Technology Division (MST-7), Los Alamos National Laboratory, Los Alamos, USA

c Materials Chemistry Division (MPA-MC), Los Alamos National Laboratory, Los Alamos, USA

Abstract

The preparation of a series of CeBr3 molecular adducts supported by the polydentate oxygen donor ligands diglyme, dimethoxyethane and tetraglyme is reported. The new complexes are characterized structurally by X-ray diffraction and optically by photoluminescence studies.

Graphical abstract: Ionic liquid mediated routes to polydentate oxygen-donor adducts of cerium(iii) bromide

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Publication details

The article was received on 02 Dec 2011, accepted on 13 Dec 2011 and first published on 23 Dec 2011


Article type: Communication
DOI: 10.1039/C2DT12333A
Citation: Dalton Trans., 2012,41, 1924-1927
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    Ionic liquid mediated routes to polydentate oxygen-donor adducts of cerium(III) bromide

    K. V. Vasudevan, N. A. Smith, B. L. Scott, B. L. Bennett, R. E. Muenchausen and J. C. Gordon, Dalton Trans., 2012, 41, 1924
    DOI: 10.1039/C2DT12333A

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