Issue 18, 2012

Tuning the coordination chemistry of a Cu(ii) complex at high-pressure

Abstract

Application of pressure on the Cu-complex CuAsp causes Jahn–Teller Cu–O bonds to be compressed, increasing the coordination environment from [4 + 1] to [4 + 2], highlighted by a discontinuity on compression of these bonding interactions.

Graphical abstract: Tuning the coordination chemistry of a Cu(ii) complex at high-pressure

Supplementary files

Article information

Article type
Communication
Submitted
30 Nov 2011
Accepted
07 Mar 2012
First published
30 Mar 2012

Dalton Trans., 2012,41, 5464-5467

Tuning the coordination chemistry of a Cu(II) complex at high-pressure

J. A. Gould, M. J. Rosseinsky and S. A. Moggach, Dalton Trans., 2012, 41, 5464 DOI: 10.1039/C2DT12302A

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