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Issue 9, 2012
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Auxiliary ligand-directed structural variation from 2D→3D polythreaded net to 3-fold interpenetrating 3D pillar-layered framework: Syntheses, crystal structures and magnetic properties

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Abstract

By auxiliary N-donor ligand-directed assembled, two entangled CoII-coordination nets have been constructed from 3,3′,5,5′-azobenzenetetracarboxylic acid (H4abtc), which present a rare 2D→3D polythreading motif constructed from 2-fold (6,3) polymeric layers with thickness being 10.2 Å and a 3-fold interpenetrating pillar-layered framework based on linear trinuclear CoII-SBUs. In addition, two CoII-complexes both show an antiferromagnetic coupling by long organic spacers and H2O bridges, respectively.

Graphical abstract: Auxiliary ligand-directed structural variation from 2D→3D polythreaded net to 3-fold interpenetrating 3D pillar-layered framework: Syntheses, crystal structures and magnetic properties

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Publication details

The article was received on 13 Nov 2011, accepted on 03 Dec 2011 and first published on 06 Jan 2012


Article type: Communication
DOI: 10.1039/C2DT12170K
Dalton Trans., 2012,41, 2560-2563

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    Auxiliary ligand-directed structural variation from 2D→3D polythreaded net to 3-fold interpenetrating 3D pillar-layered framework: Syntheses, crystal structures and magnetic properties

    J. Zhao, D. Li, X. Ke, B. Liu, K. Zou and H. Hu, Dalton Trans., 2012, 41, 2560
    DOI: 10.1039/C2DT12170K

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