Issue 2, 2012
From the journal:

Dalton Transactions

Facile in situcopper(ii) mediated C–S bond activation transforming dithiocarbimate to carbamate and thiocarbamate generating Cu(ii) and Cu(i) complexes†

Kiran Diwan,a   Bandana Singh,a   Santosh K. Singh,a   Michael G. B. Drewb  and  Nanhai Singh*a  

* Corresponding authors

a Department of Chemistry, Banaras Hindu University, Varanasi, U. P., India
E-mail: nsinghbhu@gmail.com,nsingh@bhu.ac.in
Fax: +91-542-2368127
Tel: +91-542-2307321*108

b Department of Chemistry, University of Reading, Whiteknights, Reading, UK

Abstract

Facile in situCu(II) mediated transformation of p-tolylsulfonyldithiocarbimate in conjunction with polypyridyl or phosphine ligands into corresponding carbamate and thiocarbamate led to the formation of new copper complexes with varying nuclearities and geometries, via C–S bond activation of the ligand within identical reaction systems.

Graphical abstract: Facile in situcopper(ii) mediated C–S bond activation transforming dithiocarbimate to carbamate and thiocarbamate generating Cu(ii) and Cu(i) complexes

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Article information

DOI
https://doi.org/10.1039/C1DT11622C
Article type
Communication
Submitted
28 Aug 2011
Accepted
01 Nov 2011
First published
15 Nov 2011

Dalton Trans., 2012,41, 367-369

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Facile in situcopper(II) mediated C–S bond activation transforming dithiocarbimate to carbamate and thiocarbamate generating Cu(II) and Cu(I) complexes

K. Diwan, B. Singh, S. K. Singh, M. G. B. Drew and N. Singh, Dalton Trans., 2012, 41, 367 DOI: 10.1039/C1DT11622C

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