A new conformer of indium germanate InGe3O7.5(en): conformational polymorphism in germanate family

Chun-Yang Pan; Guo-Yu Yang

doi:10.1039/C1DT11366F

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A new conformer of indium germanate InGe₃O_7.5(en): conformational polymorphism in germanate family†

Chun-Yang Pan*^ab and Guo-Yu Yang^b

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* Corresponding authors

^a Faculty of Light Industry and Chemical Engineering, Guangdong University of technology, Ghuangzhou, China
E-mail: panchuny@gdut.edu.cn

^b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on Structure of Matter of CAS, Fuzhou, Fujian Province, China

Abstract

A new conformer of indium germanate InGe₃O_7.5(en) (denoted as δ-type), constructed with the flexible unit of In₂Ge₆O₁₅N₂ was successfully prepared through a solvothermal method. The crystal data for the δ-type InGe₃O_7.5(en) are listed as follows: triclinic, space groupP-1 (No.2), a = 7.826(4) Å, b = 8.287(3) Å, c = 9.224(4) Å, α = 71.887(17)°, β = 85.343(18)°, γ = 63.734(12)°, V = 508.64 Å³, Z = 2. Four relevant conformers of indium germanate are compared with each other. The conformational polymorphism in the germanate family is reported for the first time.

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Article information

DOI: https://doi.org/10.1039/C1DT11366F
Article type: Communication
Submitted: 20 Jul 2011
Accepted: 16 Sep 2011
First published: 10 Oct 2011

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Dalton Trans., 2011,40, 11693-11695

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A new conformer of indium germanate InGe₃O_7.5(en): conformational polymorphism in germanate family

C. Pan and G. Yang, Dalton Trans., 2011, 40, 11693 DOI: 10.1039/C1DT11366F

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Dalton Transactions